Radicals and Dormant Species in Biology and Polymer Chemistry
Identifieur interne : 001444 ( Main/Exploration ); précédent : 001443; suivant : 001445Radicals and Dormant Species in Biology and Polymer Chemistry
Auteurs : Chryssostomos Chatgilialoglu [Grèce] ; Carla Ferreri [Italie] ; Krzysztof Matyjaszewski [États-Unis]Source :
- ChemPlusChem [ 2192-6506 ] ; 2016-01.
Abstract
This Review is focused on radicals and dormant species in biology and polymer chemistry. The past two decades have witnessed significant advances in understanding the role, and methods of creation and control, of free radicals in biology and polymer chemistry. The progress reached in both areas has been enabled by the mechanistic understanding and fine‐tuning of the reactivity, selectivity, and persistency of the radical species in multistep processes. The multidisciplinary scientific scenario described in this Review can be useful not only to create bridges and networks between biologists and chemists, but also to provide science with diversity, thereby highlighting aspects of biology and chemical synthesis that are only apparently far from each other. This should also result in widened scientific horizons, thus triggering a transfer from research to innovation.
Radical innovation: The past two decades have witnessed significant advances in the understanding of the role and methods of creation and control of free radicals in biological and polymerization processes. A commonality between polymers and life sciences, distant fields at first glance, can be found in their controlled radical reactivity, that is, the persistency of radical species. They resemble “Sleeping Beauty” to give marvelous results upon their awakening. The relevant convergences have been highlighted in this Review with seminal examples and parallelisms, thereby providing multidisciplinarity as a necessary driver of radical innovation in basic and applied science.
Url:
DOI: 10.1002/cplu.201500271
Affiliations:
- Grèce, Italie, États-Unis
- Attique (région), Pennsylvanie
- Athènes, Pittsburgh
- Université Carnegie-Mellon
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